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Thermodynamics and gelation of dimerizing adhesive spheres (1992)

Weist, Annemarie Ott ; Glandt, Eduardo D.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 97 (1992), S. 4316-4325

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: Wertheim's dual density formalism is applied to study the thermodynamics and gelation behavior of dimerizing adhesive spheres. Both the thermodynamic results (critical points and site–site correlation functions) and connectivity results (gelation threshold and site–site connectedness functions) are determined for mixtures of dumbbells and spheres as a function of the fraction x1 of spheres forming dumbbells, the bond length, and the degree of adhesiveness.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.463936

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