ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Photoelectron spectra of the I−⋅CH3I, I−⋅CH3Br, and I−⋅CH2Br2 complexes each display a relatively sharp main feature shifted from that of I− by the expected binding energies of the ion–dipole bound negative ions. We observe narrow photofragmentation bands in both I−⋅CH3I and I−⋅CH2Br2 upon excitation just above the photodetachment thresholds (≈3.5 eV), whose envelopes closely resemble their photoelectron spectra.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.463752