ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The discandium radical cation, Sc+2, has been isolated in neon matrices at 4 K and studied by electron spin resonance (ESR) spectroscopy and theoretical methods. It was produced by the x-irradiation of neon matrix samples containing neutral Sc2 which was formed by trapping the products generated from the pulsed laser vaporization of scandium metal. The experimental and theoretical findings indicate that Sc+2 has a 4Σ−g electronic ground state compared to an X 5Σ−u state for the neutral discandium radical. The large decrease in the 45Sc hyperfine interaction (A tensor) going from Sc2 to Sc+2 provides direct experimental information concerning the types of valence molecular orbitals that are involved in these diatomic radicals. The neon matrix magnetic parameters for 45Sc+2 are g(parallel)≈2.00, g⊥=1.960(1), ||A(parallel)||=28(6), and ||A⊥||=26.1(3) MHz; the D value (zero field splitting) was 15 381(3) MHz. Ab initio configuration interaction (CI) calculations of the nuclear hyperfine interactions yielded results in reasonable agreement with the experimental observations.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.465718
