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    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 67 (1990), S. 4536-4538 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The f-electron excitation spectra of Nd ions in superconducting NdBa2Cu3O7 and semiconducting Nd1.5Ba1.5Cu3O7 have been determined by inelastic neutron scattering. Transitions within the paramagnetic ground-state multiplet due to crystal-field splittings have been observed up to about 120 meV in these materials. The temperature dependence of the width of the low-lying transition at ∼21 meV shows significant differences in the superconducting and normal states. Adopting the CF level assignments for HoBa2Cu3O7, we rescaled the CF parameters to account for the larger radial wave functions of Nd3+ ions and obtained a level scheme for the Nd using the lowest 100 states of the f3 configuration. The calculated level structures for REBa2Cu3O7 (RE=Nd, Pr, Ho) are in good agreement with neutron and susceptibility measurements. Influence of superconducting ordering on crystal-field transitions in the Nd1+xBa2−xCu3O7 system is also discussed.
    Type of Medium: Electronic Resource
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