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Oxidation kinetics in La0.67Ba0.33MnO3−δ epitaxy on SrTiO3 (001) during pulsed-laser deposition (1999)

Zhu, X. D.

Woodbury, NY : American Institute of Physics (AIP)

Applied Physics Letters 74 (1999), S. 3540-3542

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ISSN: 1077-3118

Source: AIP Digital Archive

Topics: Physics

Notes: Using an oblique-incidence optical reflectance difference technique, we study the kinetics of La0.67Ba0.33MnO3−δ (LBMO) epitaxy on SrTiO3(001) during pulsed-laser deposition. By monitoring the recovery of the optical response function from one-monolayer-deposited LBMO, we found that under the conditions studied, the epitaxy was rate limited by the oxidation of the as-deposited monolayer with an activation barrier of 1 eV/atom or 23 kcal/mol. The result reveals the origin of oxygen deficiency often found in manganite thin films. © 1999 American Institute of Physics.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.124154

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