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Complexes of AgI with cationic ligands: bis[(pyridylmethyl)ammonio]silver(I) salts (2001)

Sailaja, Sunkari ; Swarnabala, G. ; Rajasekharan, M. V.

Oxford [u.a.] : International Union of Crystallography (IUCr)

Acta crystallographica 57 (2001), S. 1162-1165

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ISSN: 1600-5759

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: Bis[(2-pyridylmethyl)ammonio]silver(I) trinitrate, [Ag(C6H9N2)2](NO3)3, (I), and bis{bis[(4-pyridylmethyl)ammonio]silver(I)} hexakis(perchlorate) dihydrate, [Ag(C6H9N2)2]2(ClO4)6·2H2O, (II), are rare examples of complexes with cationic ligands. In (I), the Ag+ cation has a T-shaped [2+1] coordination involving the pyridine N atoms and a nitrate O atom, while in (II) there are three independent two-coordinate Ag complex cations (two with the Ag atoms on independent inversion centres) and disordered ClO4− ions. The crystal structures reveal the role of hydrogen bonding in stabilizing these complexes.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S0108270101012380

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