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(η2-Allylammonium)aquabis(sulfamato-N)copper(I) (2001)

Melnyk, Oksana P. ; Schollmeyer, Dieter ; Olijnyk, Volodymyr V. ; [et al.]

Oxford [u.a.] : International Union of Crystallography (IUCr)

Acta crystallographica 57 (2001), S. 151-153

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ISSN: 1600-5759

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: The CuI atom in the title complex, [Cu(NH2SO3)2(C3H8N)(H2O)], is coordinated by the C=C bond of the allylammonium cation, two N atoms of the sulfamate anions and the O atom of the H2O molecule in the apical position. Thus, the central atom is in a distorted trigonal–pyramidal environment. Strong N—H...O and O—H...O contacts connect separate moieties of the complex into a three-dimensional framework. The title compound is representative of hitherto unknown copper(I)–sulfamate π-complexes.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S0108270100016218

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