ALBERT — All Library Books, journals and Electronic Records Telegrafenberg

Hits per page

hit 1 - 1 | 1 hit

Select All Export

Electronic Resource

A ruthenium(II) complex with p-cymene and (S)-2-(anilinomethyl)pyrrolidine (2000)

Aitali, Mustapha ; El Firdoussi, Larbi ; Karim, Abdellah ; [et al.]

Oxford [u.a.] : International Union of Crystallography (IUCr)

Acta crystallographica 56 (2000), S. 1088-1089

add to mindlist on the mindlist

Details

ISSN: 1600-5759

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: The title compound, [(S)-2-(anilinomethyl)pyrrolidine-N,N′]-chloro(η6-para-cymene)ruthenium(II) chloride, [RuCl-(C10H14)(C11H16N2)]Cl, has been synthesized by the reaction of [RuCl2(p-cymene)]2 (p-cymene is para-isopropyltoluene) with (S)-2-(anilinomethyl)pyrrolidine in triethylamine/2-propanol. The Ru atom is in a pseudo-tetrahedral environment coordinated by a chloride ligand, the aromatic hydrocarbon is linked in a η6 manner and the amine is linked via its two N atoms. The chloride anion is involved in hydrogen bonding with the diamine moieties through N—H...Cl interactions, with N...Cl distances of 3.273 (4) and 3.352 (4) Å.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S0108270100008787

	Location	Call Number	Expected	Availability

Others were also interested in ...

Paper (German National Licenses)

Fulltext

hit 1 - 1 | 1 hit