ISSN:
1612-1112
Keywords:
Gas chromatography — atomic emission spectroscopy
;
Column liquid chromatography
;
Metal chelate chromatography
;
Diastereoisomer separation
;
Vanadium complexes
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Capillary gas chromatography with atomic emission detection (GC-AED), and high performance liquid chromatography (HPLC) have been employed to characterize isomerism of oxovanadium N,N'-propylenebis(trifluoroacetylacetoniminate). Other tetradentate Schiff base chelates of nickel, copper and palladium are also included in this study. Element-specific detection for metal and nonmetal elements in the chelates provides a means of identifying eluted peaks. Picogram detection limits for metals by GC-AED facilitated study of kinetic behavior at low concentration.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02268357
