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On the theory of adsorption kinetics of ionic surfactants at fluid interfaces 3. Generalization of the model (1991)

Dukhin, S. S. ; Miller, R.

Springer

Colloid & polymer science 269 (1991), S. 923-928

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ISSN: 1435-1536

Keywords: Adsorptionkinetics ; theory ; ionicsurfactants

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics

Notes: Abstract It was shown that, in the case of adsorbing ions, the Boltzmann equation cannot be applied in its classical form, but has to be modified by considering the flux of adsorbing ions. From the comparison with the adsorption of nonionic surfactants a ratio results which is the measure of deceleration of adsorption kinetics due to the electric double layerr=K(y s)/δ(t). At highr-values the electrostatic deceleration controls the adsorption kinetics process.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00657309

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