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Das Gleichgewicht des Cu2+−Cu+−Cu-systems in konzentrierten Perchloratlösungen (1975)

Malyszko, Jan ; Duda, Ludomir

Springer

Monatshefte für Chemie 106 (1975), S. 633-642

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ISSN: 1434-4475

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract The equilibrium of the reaction Cu2++Cu⇌2 Cu+ has been investigated in cone. solutions of Ca(ClO4)2. The apparent equilibrium constants of this reaction and the formal potentials of the Cu2+/Cu+, Cu2+/Cu and Cu+/Cu redox systems were determined. From these data the hydration numbers of the Cu2+ and Cu+ ions were estimated and the scheme of the reaction studied was proposed and discussed. In addition the equilibrium constants of the reaction Cu2++Cu(Hg)⇌2 Cu+ were calculated and discussed.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00902167

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