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Beiträge zur Chemie der Pyrrolpigmente, 49. Mitt. (1983)

Falk, Heinz ; Kapl, Gerhard ; Müller, Norbert

Springer

Monatshefte für Chemie 114 (1983), S. 773-781

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ISSN: 1434-4475

Keywords: Diastereomers ; 2,3-Dihydrobilatrienes-abc ; Kinetics ; Saturation-Transfer-Kinetics ; Phytochrome Models

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract From kinetic and equilibrium measurements the activation and thermodynamic parameters of diastereomeric 2,3-dihydrobilatrienes-abc in positions “4” and “15” are deduced. Compared to bilatrienes-abc a pronounced thermal lability of these diastereomers is observed—the exocyclic double bond of the saturated lactam ring being the more labile one. This feature may be of relevance to the thermal cascades and dark reactions observed for phytochrome.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01134188

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