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Die Kristallstruktur von TlFe3Te3 (1979)

Klepp, Kurt ; Boller, Herbert

Springer

Monatshefte für Chemie 110 (1979), S. 677-684

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ISSN: 1434-4475

Keywords: Chalkogenides ; Structural chemistry ; TlFe3Te3,crystal structure

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract TlFe3Te3 is hexagonal, space groupP63/m−C 2h 6 ,a=9.350(2) Å,c=4.2230 (7) Å,Z=2. Iron and tellurium atoms occupy the positions 6 (h) withx=0.170,y=0.149 andx=0.046,y=0.357 respectively. Thallium atoms are situated in 2 (d). The structure was determined on the basis of single crystal data obtained form a four circle diffractometer. Refinement yielded andR-value of 4.8% for an asymmetric set of 267 reflections. TlFe3Te3 is a new structure type. The structure and its relations to the Mn5Si3−, the Nb3Te4-and the Tl x V6S8-type are discussed.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00938371

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