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New telechelic polymers and sequential copolymers by polyfunctional initiator-transfer agents (Inifers) (1982)

Percec, V. ; Guhaniyogi, S. C. ; Kennedy, J. P.

Springer

Polymer bulletin 8 (1982), S. 551-555

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ISSN: 1436-2449

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics

Notes: Summary α, ω-Di(hydroxy)polyisobutylene was converted to the corresponding α,ω-di(allylether)- and α,ω-di(allylphthalyl)polyisobutylene by reacting the diol with allyl bromide in the presence of alkali and tetrabutylammonium bisulfate phase transfer catalyst, and monoallyl phthalic acid chloride in the presence of 4-N,N-dimethylaminopyridine, respectively. The reaction conditions were defined by suitable model experiments. IR and 1H-NMR analysis of the reaction products indicates quantitative conversions.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00262934

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