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Inter-versus intramolecular oligomerization of nitrile groups in polyacrylonitrile (1981)

Henrici-Olivé, G. ; Olivé, S.

Springer

Polymer bulletin 5 (1981), S. 457-461

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ISSN: 1436-2449

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics

Notes: Summary Experimental evidence is presented indicating that intermolecular oligomerization of CN groups (leading to crosslinked structures) takes place, and possibly has an even greater importance than the intramolecular reaction (leading to “ladder polymer”), at higher temperatures. The easy, quasi “built-in” crosslinking upon heat treatment is considered the most significant single feature with regard to making polyacrylonitrile and its copolymers unique among synthetic polymers as a carbon fiber precursor.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00255983

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