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Self-condensing vinyl polymerization of acrylamide (1999)

Zhang, Xi ; Liu, Weihong ; Chen, Yongming ; [et al.]

Springer

Polymer bulletin 43 (1999), S. 29-34

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ISSN: 1436-2449

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics

Notes: Summary A novel approach to branched polyacrylamide was described. The branched structure resulted from the amidyl radicals which were formed by the reaction of amide groups with Cu(III) of potassium diperiodatocuprate, K5[Cu(HIO6)2], in alkaline medium and capable of initiating the vinyl polymerization of acrylamide monomer. The obtained polymer was characterized by 1H NMR, FT-IR and intrinsic viscosity measurements.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/s002890050529

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