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Effect of 2-Chloro-1,3,2-dioxaphospholane on the radical polymerisation of acrylonitrile, styrene and methyl methacrylate (1980)

Vara Prasad, D. V. P. R. ; Mahadevan, V.

Springer

Polymer bulletin 3 (1980), S. 241-246

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ISSN: 1436-2449

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics

Notes: Abstract The effect of 2-Chloro-1,3,2-dioxaphospholane on the AIBN initiated polymerisation of acrylo — nitrile , methyl methacrylate and styrene was investigated kinetically in benzene at 60 – 80°C. With acrylonitrile normal kinetic orders with respect to monomer and AIBN could be observed with the phospholane behaving as a chain transfer agent. With methyl methacrylate and styrene it was observed that the phospholane causes enhancement of the rates due to concurrent radical and ionic polymerisation besides functioning as a chain transfer agent.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00291964

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