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Polymerization temperature effects on the properties of l-lactide and ε-caprolactone copolymers (1991)

Grijpma, D. W. ; Pennings, A. J.

Springer

Polymer bulletin 25 (1991), S. 335-341

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ISSN: 1436-2449

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics

Notes: Summary The large difference in reactivity of L-lactide and ε-caprolactone in ring opening polymerization with stannous octoate, leads to the formation of copolymers with blocky structures. By varying the polymerization temperature, copolymers with different average sequence lengths and molecular weights can be synthesized. It is shown that the average monomer sequence length has a large effect on the thermal and mechanical properties of these copolymers.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00316903

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