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The localisation model of rubber elasticity. II (1990)

Gaylord, Richard J. ; Douglas, Jack F.

Springer

Polymer bulletin 23 (1990), S. 529-533

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ISSN: 1436-2449

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics

Notes: Summary The effect of the spatial localization of a network chain by surrounding chains is incorporated into the chain probability distribution function and the network free energy is then calculated using the statistical mechanical formalism for constrained systems. In addition to a term having the classical ‘Gaussian’ form, the resulting expression contains another term which depends on both the cross-link density of the network and the plateau modulus of the uncross-linked melt.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00419973

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