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Kinetics of the liquid-phase chlorination of allyl chloride in a nonpolar solvent (1993)

Shilina, M. I. ; Barabash, V. B. ; Smirnov, V. V. ; [et al.]

Springer

Theoretical and experimental chemistry 28 (1993), S. 136-139

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ISSN: 1573-935X

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract The kinetics and mechanism of the chlorination of C3H5Cl were studied in a broad interval of temperatures and reactant concentrations. Competition was found between homolytic and nonradical chlorination of C3H5Cl in liquid phase in a nonpolar solvent. It was shown that for [C3H5Cl] 〈 0.1 M and T 〈 270 K the main reaction is the nonradical reaction, which has a negative temperature coefficient. The kinetics of the nonradical chlorination of C3H5Cl is dependent on the concentration of chlorine and is described by the sum of kinetic reactions of overall second and third orders. If [Cl2] 〉 1.5 M the main reaction is the reaction involving two molecules of chlorine and one molecule of olefin.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00573924

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