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Volumetric properties of dilute aqueous solutions of cobalt amine type salts. Part 2. Densities at 15 and 5°C (1993)

Arsuaga, Jesus M. ; Crespo, Amalia ; Núñez, Javier

Springer

Journal of solution chemistry 22 (1993), S. 361-368

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ISSN: 1572-8927

Keywords: Density ; apparent molar volume ; aqueous solutions ; trisethylenediaminocobalt(III) chloride and bromide ; tris-propylene-diaminocobalt(III) chloride and bromide ; tris-trimethylenediaminocobalt(III) chloride and bromide ; hydrophobic interaction

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Apparent molar volumes have been determined by density measurements of aqueous solutions for a series of salts [Co(L)3]X3, where X=Cl− and Br− and L1=1,2-diaminoethane (en), L2=1,2-diaminopropane (pn) and L3=1,3-diaminopropane (tn) at 15°C and 5°C. Apparent molar volumes at infinite dilution for the complex cations at 0°C are estimated. The resulting values are related to the structure of solvent water molecules around the ions.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00647208

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