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Vapor-liquid equilibria forn-tetradecane-benzene mixtures at 25 and 50°C (1982)

Rubio, R. G. ; Renuncio, J. A. R. ; Diaz Peña, M.

Springer

Journal of solution chemistry 11 (1982), S. 823-830

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ISSN: 1572-8927

Keywords: Excess Gibbs free energy ; activity coefficient at infinite dilution ; benzene ; alkane ; Pade approximant ; n-tetradecane ; vapor pressures

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Vapor pressures for the benzene+n-tetradecane system have been measured using a static apparatus. The excess Gibbs free energy was calculated using a modified Barker method and a Pade approximant equation. The selection of the most adequate approximation is discussed. Results are compared with those corresponding to other thermodynamic properties. The activity coefficient of benzene at infinite dilution calculated from these data agrees well with the value obtained from the literature.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00650521

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