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Molecular structure of ThBr4(DME)2 (DME = 1,2-dimethoxyethane) (1999)

Rabinovich, Daniel ; Scott, Brian L. ; Nielsen, Jon B. ; [et al.]

Springer

Journal of chemical crystallography 29 (1999), S. 243-246

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ISSN: 1572-8854

Keywords: Thorium ; dimethoxyethane ; crystal structure

Source: Springer Online Journal Archives 1860-2000

Topics: Geosciences , Physics

Notes: Abstract The molecular structure of ThBr4(DME)2 (DME = 1,2-dimethoxyethane), the first structurally characterized thorium complex containing a simple bidentate ether ligand, is described. The eight-coordinate complex presents a distorted dodecahedral geometry, with Th—Br and Th—O bond lengths in the ranges 2.8516(13)–2.8712(13) Å and 2.564(8)–2.620(8) Å, respectively. ThBr4(DME)2 is monoclinic, space group P21/n, a = 7.672(1), b = 14.581(1), c = 15.847(2) Å, β = 102.24(1)°, V = 1732.4(3) Å3, and Z = 4.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1023/A:1009542715804

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