ISSN:
1572-8854
Keywords:
Tripodal ligand
;
Ni(II) complex
;
quinoline
;
carbinoxyamine
;
structure
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract Treatment of Ni(ClO4)2 · 6H2O with the condensing product of 2-formylpyridine N-oxide and 1,5-diamino-3-(8-methylquinolyl)azapentane (dmqa) has resulted in the formation of an asymmetric tripodal nickel(II) complex, [C28H32N6O3Ni](ClO4)2 · H2O, which has been crystallographically characterized. Crystal data: triclinic, space group p ī, a = 10.384(2), b = 10.911(3), c = 16.6101(11) Å, α = 95.62(2), β = 105.04(2), γ = 112.954(11)°, D c = 1.581 g/cm3, Z = 2 and V = 1631.0(6) Å3. A quinoline moiety is first introduced into an arm in the complex of a tripodal ligand in which an ethylcarbinoxyamine group, the intermediate of Schiff bases, exists.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1009578329008
