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Unusual occurrence of photooxidation of a cage diol (1995)

Bott, Simon G. ; Marchand, Alan P. ; Liu, Zenghui

Springer

Journal of chemical crystallography 25 (1995), S. 295-298

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ISSN: 1572-8854

Keywords: Cage-diol ; crystal structure ; photooxidation

Source: Springer Online Journal Archives 1860-2000

Topics: Geosciences , Physics

Notes: Abstract An unusual photooxidation was noted upon photolytic cage closure of a substituted tricyclo[6.2.1.02.7]undecane-exo, exo-diol. The resultant compound, which may be regarded as a mono-reduced pentacyclo[5.4.0.02,6.03,10.05,9]undecane-8,11-dione, was characterizedvia X-ray crystallography. This species could be reduced to the tricyclo[6.2.1.02,7]undecane-endo, exo-diol under conditions previously shown to be inert for the parent dione.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01796053

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