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An association model for mixtures containing any number of alkanes and any number of alcohols: Application to alcohol-alkane binary systems (1995)

Schmidt, C. A. ; Campbell, S. W.

Springer

International journal of thermophysics 16 (1995), S. 1299-1307

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ISSN: 1572-9567

Keywords: alcohols ; alkanes ; association ; hydrogen bonding ; vaporliquid equilibrium

Source: Springer Online Journal Archives 1860-2000

Topics: Physics

Notes: Abstract A previously derived association model for mixtures of any number of alcohols and alkanes is applied here to alcohol-alkane binary systems. The model contains two adjustable parameters: a self-association constant for the alcohol and a parameter that reflects physical interactions. Correlations for the two parameters are presented which allow the model to be used as a two-, one-, or zero-parameter model, depending on the amount of experimental data available. All three forms of the model provide adequate results for these systems over a fairly wide temperature range.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF02081297

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