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The effects of rare earth oxides on the reverse water-gas shift reaction on palladium/alumina (1994)

Pettigrew, D. J. ; Trimm, D. L. ; Cant, N. W.

Springer

Catalysis letters 28 (1994), S. 313-319

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ISSN: 1572-879X

Keywords: reverse water-gas shift ; palladium ; ceria ; lanthana ; praesodymia

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract The interaction between palladium and ceria, both supported on alumina, has been explored in the context of the reverse water-gas shift reaction. Specific rates of reaction were greater over catalysts containing ceria. The reaction kinetics were consistent with reaction between dissociatively adsorbed hydrogen and dissociatively adsorbed carbon dioxide, a reaction which is accelerated by migration of adsorbed oxygen across the metal surface to the ceria surface.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00806061

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