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Peroxide derivatives of molybdenum(VI) in neutral and alkaline media (1989)

Csányi, László J. ; Horváth, István ; Galbács, Zoltán M.

Springer

Transition metal chemistry 14 (1989), S. 90-94

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ISSN: 1572-901X

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Summary The peroxidation of molybdenum(VI) was investigated in neutral and alkaline media. The stability constants of the peroxo complexes were determined by spectrophotometric measurement as (9.12±0.67)×10−7, (2.68±0.17) ×105, (1.26±0.06)×106 and (1.58±0.02) for the 1∶1, 2∶1 (yellow), 3∶1 and 4∶1 (red) species. The diperoxomolybdate disproportionates into the tetraperoxo derivative when treated with alkali. Formation of the tetraperoxo complex was found to be pH dependent according to a curve, with maximum at pH 10. Acidification of tetraperoxomolybdate solution results in the regeneration of hydrogen peroxide and the diperoxo complex is reformed.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01040598

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