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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Reaction kinetics and catalysis letters 4 (1976), S. 307-313 
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Окисление метанола на хромомолибденовом окисном катализаторе идет по схеме: $$CH_3 OH\xrightarrow[{W_1 }]{{O_2 }}CH_2 O\xrightarrow[{W_2 }]{{O_2 }}CO$$ Кинетические уравнения имеют вид: для окисления метанола $$W_1 = \frac{{K_1 C_{CH_3 OH} }}{{1 + a_1 C_{CH_3 OH + a_2 } C_{H_2 O} }}$$ для окисления формальдегида $$W_2 = K_2 C_{CH_2 O} $$
    Notes: Abstract Oxidation of methanol on a chromium-molybdenum oxide catalyst proceeds via the scheme: $$CH_3 OH\xrightarrow[{W_1 }]{{O_2 }}CH_2 O\xrightarrow[{W_2 }]{{O_2 }}CO$$ The following kinetic equations have been obtained $$W_1 = \frac{{K_1 C_{CH_3 OH} }}{{1 + a_1 C_{CH_3 OH + a_2 } C_{H_2 O} }}$$ for the oxidation of methanol, and $$W_2 = K_2 C_{CH_2 O} $$ for the oxidation of formaldehyde.
    Type of Medium: Electronic Resource
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