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Phase Diagram of EC–DMC Binary System and Enthalpic Determination of Its Eutectic Composition (2000)

Ding, M. S. ; Xu, K. ; Jow, T. R.

Springer

Journal of thermal analysis and calorimetry 62 (2000), S. 177-186

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ISSN: 1572-8943

Keywords: binary phase diagram ; DSC ; enthalpic method ; eutectic composition

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract We construct with a differential scanning calorimeter (DSC) a phase diagram for the ethylene carbonate (EC)-dimethyl carbonate (DMC) binary system for its liquid-solid phase equilibria. We determine the eutectic composition of the binary system using an enthalpic method that we devised based on the composition dependence of the enthalpy of solidus melting, with highly consistent results. We also discuss the merits and limitations of this enthalpic method.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1023/A:1010175114578

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