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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of inclusion phenomena and macrocyclic chemistry 11 (1991), S. 389-396 
    ISSN: 1573-1111
    Keywords: Clathrate ; quinol/SO2 clathrate ; Raman spectroscopy ; pre-resonance Raman effect
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A pre-resonance Raman study of the yellow β-quinol/SO2 clathrate has been carried out using 609.8, 586.8, 514.5, 488.0 and 457.9 run excitation. Pre-resonance enhancement is observed for the guest vl (Al) band at 1147 cm−1 and the host band at 1257 cm−1. These observations are consistent with a charge transfer interaction arising from the LUMO of S02 (S 3pz) and the HOMO of quinol, which consists mainly of the ring π electrons.
    Type of Medium: Electronic Resource
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