ISSN:
1572-9540
Source:
Springer Online Journal Archives 1860-2000
Topics:
Physics
Notes:
Abstract The nuclear quadrupole interactions of27Al and67Zn, both at the B-site in the spinel ZnAl2O4 have been studied using the Hartree-Fock cluster procedure including the influence of the ions outside the cluster. The theoretical value −3.85 MHz ofe 2 qQ for27Al is in very good a agreement with the experimental value of 3.68 MHz (sign undetermined). For67Zn at the Al site the theoretical value is −8.26 MHz in reasonable agreement with the experimental value of −11.34 MHz indicating that lattice distortion effects associated with Zn as an impurity at the Al site are relatively small.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00568165