ISSN:
1572-8838
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Electrical Engineering, Measurement and Control Technology
Notes:
Abstract This paper is concerned with mass transfer to a rotating disc electrode (RDE) under pulsed potential and pulsed current conditions. For the case of pulsed potential, a numerical solution is presented to calculate the instantaneous current density for intermediate and large cycle times and an asymptotic solution for short cycle times. The special case of applying a step potential is then presented. The magnitude of the step current for a given transition time is calculated from the numerical solution by Viswanathanet al. for the pulsed current case. Comparison is made between the present results and various approximate solutions from the literature.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00610939
