ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Preferential formation of di- or trimers of methylenecyclopropane (MCP) under the influence of Ni(O) complexes is determined by the nature of ligands, additions of modifiers, and the reaction conditions. The Ni(O) complex with coordinated P(NEt2)3 was synthesized via a proposed intermediate catalytic system Ni(COD)2-P(NEt2)3 by the interaction between Ni(η3-C3H5)2 and P(NEt2)3. The composition of the complex: {Ni[P(NEt2)3]2 x} (K-1) was established by1H and31P-1H NMR, EPR spectroscopy, IR diffuse reflectance spectroscopy, and GLC. In the range 20–60
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00957976