ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract A method was proposed for the synthesis of acylketene N,N-acetals (AKA) by the action of methanol in the presence of Co2+ acetate on diacylketene N,N-acetals. Using1H and13C NMR spectroscopy, a restrainment of the internal rotation around the C=C bond of AKA was discovered, and the influence of solvation of the dynamic equilibrium of the E- and Z-isomers was studied.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00960665