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Oxidation of coordination compounds of Pd(II) with 1,2-hydroxylaminooximes (1986)

Larionov, S. V. ; Kosareva, L. A. ; Boguslavskii, E. G.

Springer

Russian chemical bulletin 35 (1986), S. 1924-1927

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ISSN: 1573-9171

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Conclusions 1. The oxidative dehydrogenation of complexes of palladium(II) with 1,2-hydroxylamino-oximes results in the formation of compounds containing exchange-coupled radical anions, while the oxidation of the complex of palladium chloride with a molecule of a 1,2-hydroxylaminooxime is accompanied by the conversion of the ligand into a nitroso compound. 2. New volatile chelates can be obtained by a method involving the oxidative dehydrogenation of complexes with 1,2-hydroxylaminooximes.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00954034

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