ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. A method of approximate a priori evaluation of the influence of pressure upon the rate of chemical reactions in solution was proposed on the basis of the linear relationship between the rate constants of reactions at high pressures, previously found by the authors. 2. The prospects of organic synthesis at high pressures were analyzed. It was concluded that there are broad possibilities of accomplishing syntheses that practically do not take place at atmospheric pressure in high yields at high pressure, as well as a possibility of using high pressure to change the structural and steric direction of reactions. 3. Evidently the region of pressures 5000–15,000 atm is the most promising for searches for new liquid-phase reactions.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01176024
