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Polymerization of 2-chloroacrolein (1966)

Belyaev, V. I. ; Annenkova, V. Z. ; Ugryumova, G. S. ; [et al.]

Springer

Russian chemical bulletin 15 (1966), S. 1202-1204

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ISSN: 1573-9171

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Conclusions 1. The polymerization of 2-chloroacrolein was carried out for the first time by ionic and radical mechanisms. The properties of the polymers obtained were studied. 2. The radical polymerization of 2-chloroacrolein in the presence of a redox system goes at carbon-carbon bonds with formation of a poly-2-chloroacrolein with a molecular weight of greater than 70,000. In polymerization by an ionic mechanism in the presence of stannous chloride and by a radical mechanism in the presence of hydrogen peroxide 2-chloroacrolein polymers of low molecular weight (oligomers) were formed. 3. In the UV irradiation of the polymer in the presence of a sensitizer (butanone), a change in some of its properties is observed.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00847764

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