ISSN:
0887-624X
Keywords:
radical
;
polyaddition
;
spiroacetal
;
bifunctional vinylcyclopropane
;
dithiol
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Radical polyadditions of vinylcyclopropane having spiroacetal moiety, 1,10-divinyl-4,8,12,15-tetraoxatrispiro[2.2.2.2.2.2] pentadecane (1), and various dithiols were examined. 1 was prepared by the reaction of 1,1-dichloro-2-vinylcyclopropane and pentaerythritol, and radical polyadditions of 1 and dithiols were carried out at 60 and 120°C for 20 h in the presence of an appropriate initiator (3 mol % vs. 1) in degassed sealed ampoules or at 20°C under photo irradiation by using a 400 W high-pressure mercury lamp. Poly(1), pale yellow transparent viscous polymers was isolated by reprecipitation with ether containing a small amount of triethylamine to avoid hydrolysis of the polymer. The obtained polymers were soluble in chlorobenzene, DMF, and chloroform but insoluble in ether and n-hexane. The molecular weights of the polymers obtained from aliphatic dithiols were smaller than those from aromatic ones. The structure of the polymer was determined by comparing the NMR spectra with those of the model compounds, which were obtained by radical addition of 1 and benzyl mercaptan. The reaction proceeded through radical polyaddition of dithiol to 1 via radical ring-opening polymerization of the cyclopropane ring. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 2487-2492, 1997
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
