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Synthesis of polyphthalocyanines by an oxido-reduction reaction initiated by the benzhydrol functional group. II. Polymer study (1989)

Pascal, Thierry ; Malinge, Jean ; Sillion, Bernard

Bognor Regis [u.a.] : Wiley-Blackwell

Journal of Polymer Science Part A: Polymer Chemistry 27 (1989), S. 2777-2791

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ISSN: 0887-624X

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Three new bis(phthalonitrile) monomers carrying flexible aliphatic polyether sequences were synthesized and thermally polymerized to yield crosslinked poly(metal-free phthalocyanine) networks. The procedure of thermal conversion of bis(phthalonitrile) monomers involved an oxidoreduction reaction initiated by the alcohol functional group of a benzhydrol phthalonitrile coreactant. The phthalocyanine polymeric networks were characterized by FT-IR, TGA, TMA, and x-ray diffraction. Their electrical dc conductive properties were studied in a pure and an iodine-doped state.

Additional Material: 7 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pola.1989.080270822

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