ISSN:
0887-6266
Schlagwort(e):
hydrodynamics
;
crossover
;
thermal blob
;
apparent exponents
;
Physics
;
Polymer and Materials Science
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
,
Physik
Notizen:
The scaling predictions for the temperature dependence of the intrinsic viscosity of flexible polymers are briefly reviewed. When the predictions are fit to a power law over a fixed range of chain length, a relation between the exponent and prefactor of the Mark-Houwink-Sakurada equation emerges. In comparing with the experimental data compilation of Rai and Rosen, we conclude that real polymer systems are nowhere near the true good solvent limit, even when the exponent matches the good solvent prediction. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 1989-1991, 1997
Zusätzliches Material:
3 Ill.
Materialart:
Digitale Medien
