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CO2 sorption in uniaxially drawn atactic polystyrene (1986)

Carfagna, C. ; Nicodemo, L. ; Nicolais, L. ; [et al.]

Bognor Regis [u.a.] : Wiley-Blackwell

Journal of Polymer Science Part B: Polymer Physics 24 (1986), S. 1805-1812

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ISSN: 0887-6266

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The CO2 solubility in oriented and unoriented atactic polystyrene films has been investigated. Orientation does not change the nature of the sorption process; however, it decreases the level of solubility. Both the Langumir sorption term and the Henry's-law contribution are affected by orientation. The decrease of solubility is correlated with an increase of density due to orientation. A simple experiment has been described to evaluate the depression of the glass transition temperature of polystyrene containing dissolved carbon dioxide.

Additional Material: 7 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/polb.1986.090240815

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