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A far-infrared study of ionic interactions in poly(styrene sulfonic acid) ionomers (1984)

Mattera, Vincent D. ; Risen, William M.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Physics Edition 22 (1984), S. 67-77

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ISSN: 0098-1273

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The far-infrared spectra of poly(styrene sulfonic acid) (PSSA) ionomer films containing alkaline and alkaline earth ions have been studied, and strong, broad bands, whose frequencies are cation dependent, have been observed and assigned to cation motion. The force field elements for cations vibrating at sulfonate-containing sites have been obtained for different models of the cation-motion vibration. The effects of hydration, dehydration, and thermal annealing are discussed in light of ion clustering in these materials.

Additional Material: 7 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1984.180220107

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