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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 15 (1977), S. 1619-1626 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Polydioxolan samples crystallized between 25 and 35°C present two optical phases when viewed on the polarizing microscope. These phases, termed central and external phases, form a spherulite. It is shown in this paper that the central phase of the two-phase spherulite melts at about 63°C, and is made of modification III crystals. The external portion of the two-phase spherulites melts at a lower temperature, around 59°C, and is composed of modification II crystals. Differential scanning calorimeter (DSC) melting curves, photomicrographs, and x-ray results are presented to prove these assertions.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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