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Diffusion in polymer-solvent systems. III. Construction of Deborah number diagrams (1977)

Vrentas, J. S. ; Duda, J. L.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Physics Edition 15 (1977), S. 441-453

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ISSN: 0098-1273

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: A method is presented for anticipating condition under which anomalous diffusion effects can be expected for amorphous polymer-solvent systems. The diffusion process is characterized by a dimensionless group called the diffusion Deborah number, and a method for calculating this dimensionless number is presented. Deborah number diagrams are constructed for the unsteady diffusion of ethylbenzene and polystyrene in thin films, and observed diffusion phenomena are discussed on the basis of these diagrams.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1977.180150304

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