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Relation between preferential solvation and intrinsic viscosity of polymers in solvent mixtures (1977)

Dondos, A. ; Benoît, H.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Physics Edition 15 (1977), S. 137-144

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ISSN: 0098-1273

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Preferential solvation and intrinsic viscosity measurements are reported for three systems: polystyrene + benzene + methanol, polystyrene + carbon tetrachloride + methanol, and poly(2-vinylpyridine) + ethanol + cyclohexane. Plots of the coefficient of preferential solvation λ′ as a function of variation of the segment density Δρ for a given ternary system, give a single curve for a large range of molecular weight and solvent mixture composition. This correlation between λ′ and Δρ is verified in previously published data.

Additional Material: 9 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1977.180150112

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