ISSN:
0098-1273
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Samples of n-hexatriacontane irradiated in the crystalline and molten states were compared as regards the GPC chromatograms of the partially crosslinked products. From differences in the elution volumes it could be inferred that there is a greater trend for random linking along the chain in the sample irradiated in the melt as opposed to preference for end-type linking in the samples irradiated as crystals. In the course of this work the applicability of the GPC technique for detecting short (methyl) branches and for distinguishing between the position of these branches along the chain has also become apparent.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1975.180130210
