ISSN:
0025-116X
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
A series of AB diblock copolymers of poly(2-vinylpyridine) (P-2VP) and either polybutadiene or polystyrene were prepared in a nonpolar solvent at low temperature. Well-defined polymers with narrow molecular weight distributions were obtained and electron micrographs showed that these block copolymers form a well-separated two-phase morphology. Percolation of P-2VP domains could be achieved for samples with 40 and with 60 mol-% of P-2VP blocks. These samples were modified by addition of various amounts of iodine in solution and in the melt. Electric conductivities of the doped composites were determined by the four-probe method. The conductivities of the two phase systems were, in general, lower than that of P-2VP doped with I2.
Additional Material:
10 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1989.021900521