ISSN:
0025-116X
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Mechanism and kinetics of the reactions of N-(2,3-epoxypropyl)-N-methylaniline (1) with aniline or 4,4′-sulfonyldianiline (3) were investigated using high performance liquid chromatography and 13C FT NMR under different conditions (110-172°C). Comparison of 1 with its derivatives shows that the activity of the 2,3-epoxypropyl group in such epoxides depends on the structure and the substituents at the benzene ring; etherification may occur already before the secondary amine is consumed.
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1987.021881108