ISSN:
0025-116X
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
3,4-Methylenedioxybenzyl methacrylate (3) was synthesized from 3,4-methylenedioxybenzyl alcohol (2) and methacryloyl chloride. 3 was radically polymerized with tributylborane and copolymerized in cyclohexanone at room temperature under nitrogen. The following monomer reactivity ratios were determined M1 = 3: r1 = 0,68 and r2 = 0,40 for M2 = styrene, r1 = 0,78 and r2 = 0,16 for M2 = acrylonitril, and r1 = 0,28 and r2 = 1,47 for methyl methacrylate. Polymeric derivatives having 3,4-dihydroxybenzyl units in the side chains were prepared from homo- and copolymers of 3. The thermal stability and redox behaviour of these polymers were investigated.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1981.021821018